Soft X-ray emission spectroscopy of early transition metal compounds
Soft X-ray emission studies for several early transition metal compounds, such as Sc, Ti and V compounds, have been studied. Raman scattering was found at the 2p → 3d excitation in the transition metal compounds. The elementary excitation of the Raman spectrum is mainly elucidated by the d-d transition within the 3d bands, as well as the interband transition from the O 2p valence band to the conduction band, which consists mainly of transition metal 3d states. The charge transfer transition due to the localized electron picture is dominant in the soft X-ray spectra of Sc compounds. Raman scattering is a powerful tool in the study of the electronic structure of transition metal compounds. © 1998 Elsevier Science B.V. All rights reserved.
Publication Source (Journal or Book title)
Journal of Electron Spectroscopy and Related Phenomena
Shin, S., Fujisawa, M., Ishii, H., Harada, Y., Watanabe, M., Grush, M., Callcott, T., Perera, R., Kurmaev, E., Moewes, A., Winarski, R., Stadler, S., & Ederer, D. (1998). Soft X-ray emission spectroscopy of early transition metal compounds. Journal of Electron Spectroscopy and Related Phenomena, 92 (1-3), 197-205. https://doi.org/10.1016/s0368-2048(98)00122-4