Document Type
Article
Publication Date
11-14-2013
Abstract
We calculated magnetic exchange constants and magnetocaloric properties of Ni2Mn1-xCuxGa Heusler alloys by ab initio and Monte Carlo methods. The ab initio study of the influence of the Cu excess x on the strength of magnetic interactions revealed that Cu weakens Mn-Ni interaction and has a complex impact on the Mn-Mn interactions. Theoretically calculated magnetic phase diagram of Ni2Mn1-xCuxGa is in a good agreement with available experimental data. Calculated by the Monte Carlo method the isothermal magnetic entropy change Δ S m a g in a Ni2Mn0.75Cu0.25Ga alloy is significantly smaller around the coupled magnetostructural phase transition temperature than the reported earlier experimental Δ S m a g. This discrepancy is ascribed to an overestimation of the experimental Δ S m a g at the magnetostructural phase transition. Theoretically determined adiabatic temperature change Δ T a d in Ni2Mn 0.75Cu0.25Ga agrees well with Δ T a d measured experimentally by a direct method. © 2013 AIP Publishing LLC.
Publication Source (Journal or Book title)
Journal of Applied Physics
Recommended Citation
Sokolovskiy, V., Buchelnikov, V., Skokov, K., Gutfleisch, O., Karpenkov, D., Koshkid'Ko, Y., Miki, H., Dubenko, I., Ali, N., Stadler, S., & Khovaylo, V. (2013). Magnetocaloric and magnetic properties of Ni2Mn 1-xCuxGa Heusler alloys: An insight from the direct measurements and ab initio and Monte Carlo calculations. Journal of Applied Physics, 114 (18) https://doi.org/10.1063/1.4826366