Photon-stimulated desorption of H+ ions from OH on Ti and Cr: Comparison with bulk solid H2O

Authors

E. Bertel, National Institute of Standards and Technology
D. E. Ramaker, National Institute of Standards and Technology
R. L. Kurtz, National Institute of Standards and Technology
R. Stockbauer, National Institute of Standards and Technology
T. E. Madey, National Institute of Standards and Technology

Document Type

Article

Publication Date

1-1-1985

Abstract

An interpretation and comparison of photon-stimulated desorption yields of H+ ions from OH on Ti and Cr and from bulk solid H2O indicate that desorption occurs through two entirely different mechanisms. The first involves in intramolecular excitation of the OH adsorbate producing a H+ yield similar to that in bulk H2O. The second involves metal core-level excitation followed by Auger decay and is an example of molecular adsorbate dissociation arising from a metal-substrate Auger decay. This is a further generalization of the Knotek-Feibelman model applicable for desorption in ionic systems. © 1985 The American Physical Society.

Publication Source (Journal or Book title)

Physical Review B

First Page

6840

Last Page

6842

Recommended Citation

Bertel, E., Ramaker, D., Kurtz, R., Stockbauer, R., & Madey, T. (1985). Photon-stimulated desorption of H+ ions from OH on Ti and Cr: Comparison with bulk solid H2O. Physical Review B, 31 (10), 6840-6842. https://doi.org/10.1103/PhysRevB.31.6840