Identifier

etd-10162016-085326

Degree

Master of Science (MS)

Department

Chemistry

Document Type

Thesis

Abstract

This master’s thesis discusses developments of novel organic methodologies utilizing oxyallyl cationic systems in the pursuit of highly functionalized molecular scaffolds. Chapter 1 focuses on the discovery of the oxyallyl cation intermediate, and examines reported transformations. Detailed optimization and substrate studies following exploitation of a protected 2-oxyallyl cation for nucleophilc capture comprises the information in both Chapter 2 and Chapter 3. Chapter 4 extends methodologies performed by my colleagues and establishes a tandem process using 2-silyloxypentadienyl cations to furnish complex structures. In this report, reaction design and optimization are chronicled, followed by exploration into the reactivity, mechanism, and scope of the developed reactions.

Date

2016

Document Availability at the Time of Submission

Release the entire work immediately for access worldwide.

Committee Chair

Kartika, Rendy

Included in

Chemistry Commons

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