Multiple H 2 occupancy of cages of clathrate hydrate under mild conditions
Experiments were carried out by reacting H 2 gas with N 2 hydrate at a temperature of 243 K and a pressure of 15 MPa. The characterizations of the reaction products indicated that multiple H 2 molecules can be loaded into both large and small cages of structure II clathrate hydrates. The realization of multiple H 2 occupancy of hydrate cages under moderate conditions not only brings new insights into hydrogen clathrates but also refreshes the perspective of clathrate hydrates as hydrogen storage media. © 2012 American Chemical Society.
Publication Source (Journal or Book title)
Journal of the American Chemical Society
Lu, H., Wang, J., Liu, C., Ratcliffe, C., Becker, U., Kumar, R., & Ripmeester, J. (2012). Multiple H 2 occupancy of cages of clathrate hydrate under mild conditions. Journal of the American Chemical Society, 134 (22), 9160-9162. https://doi.org/10.1021/ja303222u