Title

Electronic spectrum and crystal structure of fac-MoOCl3(dppe)

Document Type

Article

Publication Date

1-1-1998

Abstract

X-ray analysis of the oxomolybdenum(V) complex MoOCl3(dppe) (dppe = 1,2-bis(diphenylphosphino)ethane) shows that it is the facial isomer. (C26H24Cl1MoOP2, space group P21/n, a = 13.217(1), b = 12.8935(8), c = 16.0578(9) Å, β= 99.967(5)°, V = 2695.1(6) Å3, Z = 4, R = 0.038 for 6228 data with l > 1σ(I).) The electronic absorption spectrum of the title compound is also compared with those of other oxomolybdenum(V) complexes. © 1998 Elsevier Science Ltd. All rights reserved.

Publication Source (Journal or Book title)

Polyhedron

First Page

1617

Last Page

1620

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