Title
Porous Cu-Cd mixed-metal-organic frameworks constructed from Cu(Pyac) 2 {Bis[3-(4-pyridyl)pentane-2,4-dionato] copper(II)}
Document Type
Article
Publication Date
12-27-2004
Abstract
Porous Cu-Cd mixed-metal-organic frameworks [{Cd(NO3) 2}2-{(Cu(Pyac)2}3] (M′MOF 1) and [{CdCl2}{Cu(Pyac)2}2] (M′MOF 2) {Cu(Pyac)2 = bis[3-(4-pyridyl)pentane-2,4-dionato] copper(II)} have been synthesized by the reaction of Cu(Pyac)2 with Cd(NO 3)2 and CdCl2. They are noninterpenetrating 1D ladder and 2D square-grid frameworks, constructed from Cu(Pyac)2 building blocks with T-shaped Cd(NO3)2 nodes and square-planar CdCl2 nodes, respectively. The 1D ladders and 2D square grids are stacked in ABCABC... and ABCDEF... packings, leading to 2D interconnected channels of ca. 5.7 × 10.2 and 4.1 × 9.8 Å in 1 and 1D channels of ca. 8.0 × 8.2 Å in 2, respectively. The copper sites in these two M′MOFs are coordinated by solvent molecules and exposed to the pores.
Publication Source (Journal or Book title)
Inorganic Chemistry
First Page
8209
Last Page
8211
Recommended Citation
Chen, B., Fronczek, F., & Maverick, A. (2004). Porous Cu-Cd mixed-metal-organic frameworks constructed from Cu(Pyac) 2 {Bis[3-(4-pyridyl)pentane-2,4-dionato] copper(II)}. Inorganic Chemistry, 43 (26), 8209-8211. https://doi.org/10.1021/ic048992n