Title

Copper β-diketonate molecular squares and their host-guest reactions

Document Type

Article

Publication Date

9-3-2007

Abstract

(Figure Presented) All square: Treatment of m-phenylene-bis(β- diketones) with [Cu(NH3)4]2+ yields molecular squares rather than the expected hexagons. The squares react readily with guests such as C60 (see structure) and 4,4′-bipyridine. They are also effective for the storage of H2 gas, both at 77 K and at room temperature. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

Publication Source (Journal or Book title)

Angewandte Chemie - International Edition

First Page

6305

Last Page

6308

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