Title

Quantifying chloride binding and salt extraction with poly(methyl methacrylate) copolymers bearing aryl-triazoles as anion receptor side chains

Document Type

Article

Publication Date

11-11-2014

Abstract

© 2014 the Partner Organisations. Copolymers of methyl methacrylate and aryl-triazole based anion receptors were quantitatively analyzed. Transfer of structural features (1:1 and 2:1 complexes) and Cl- affinities from the parent receptors was demonstrated. Cl--induced cross-linking changed the polymer's hydrodynamic radius. Extraction of tetrapropylammonium Cl- from water to dichloromethane was enhanced over PMMA.

Publication Source (Journal or Book title)

Chemical Communications

First Page

13285

Last Page

13288

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