Title

Synthesis of Cycloparaphenyleneacetylene via Alkyne Metathesis: C70 Complexation and Copper-Free Triple Click Reaction

Document Type

Article

Publication Date

10-26-2016

Abstract

© 2016 American Chemical Society. Alkyne metathesis provided an efficient macrocyclization route to a cycloparaphenyleneacetylene derivative in high yield. The cavity size was suitably matched for C70 which was tightly bound in an induced-fit fashion. The strained alkynes enabled a copper-free, 3-fold azide-alkyne cycloaddition at 50 °C.

Publication Source (Journal or Book title)

Journal of the American Chemical Society

First Page

13814

Last Page

13817

This document is currently not available here.

Share

COinS