Title

Versatile functionalization of carbon electrodes with a polypyridine ligand: Metallation and electrocatalytic H+ and CO2 reduction

Document Type

Article

Publication Date

2-18-2015

Abstract

© The Royal Society of Chemistry 2015. A strategy is proposed for immobilization of homogeneous catalysts whereby a glassy carbon electrode is functionalized by electro-grafting of a ligand, terpyridine. The modified electrode can easily be metallated with cobalt and shows activity towards catalytic proton and CO2 reduction. The metal can be removed and the electrode re-metallated at will.

Publication Source (Journal or Book title)

Chemical Communications

First Page

2995

Last Page

2998

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