Title
Aluminum, gallium, germanium, copper, and phosphorus complexes of meso -triaryltetrabenzocorrole
Document Type
Article
Publication Date
4-1-2013
Abstract
5,10,15-Triaryltetrabenzocorrole complexes of aluminum, gallium, germanium, and phosphorus were synthesized by coordination of these metal ions in the preformed triaryltetrabenzocorrole macrocycle, opening a way to the investigation of different metal complexes. The UV-vis spectra of these derivatives exhibit a red shift and broadening of all absorption bands because of the π-extended aromatic system and distortion of the molecular framework. The electrochemical and photophysical behaviors of the free base and the metal complexes of meso-triaryltetrabenzocorrole were investigated and characterized. © 2013 American Chemical Society.
Publication Source (Journal or Book title)
Inorganic Chemistry
First Page
4061
Last Page
4070
Recommended Citation
Pomarico, G., Nardis, S., Naitana, M., Vicente, M., Kadish, K., Chen, P., Prodi, L., Genovese, D., & Paolesse, R. (2013). Aluminum, gallium, germanium, copper, and phosphorus complexes of meso -triaryltetrabenzocorrole. Inorganic Chemistry, 52 (7), 4061-4070. https://doi.org/10.1021/ic400162y