Title

π-π Aggregation in metalloporphyrins: Causative factors

Document Type

Article

Publication Date

12-1-1976

Abstract

The strength of aggregation in PdII, NiII, Zn II, and CdII metalloporphyrins is shown by n.m.r. spectroscopy to depend upon interaction of the metal ion with the porphyrin π-system; within a selected series of 2,4-disbustituted deuteroporphyrin-IX dimethyl esters complexed with a constant metal ion the aggregation is further enhanced by the presence of electron-withdrawing substituents on the porphyrin periphery.

Publication Source (Journal or Book title)

Journal of the Chemical Society, Chemical Communications

First Page

699

Last Page

701

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