Title

Mercuration reactions of porphyrins: New efficient syntheses of harderoporphyrin and isoharderoporphyrin

Document Type

Article

Publication Date

1-1-1980

Abstract

Treatment with mercury(II) acetate of metal complexes of porphyrins bearing peripherally unsubstituted positions gives the corresponding mercurated derivatives, using the palladium-olefin reaction this observation is exploited in the synthesis of coproporphyrin III tetramethyl ester (2), harderoporphyrin trimethyl ester (3), and isoharderoporphyrin trimethyl ester (4).

Publication Source (Journal or Book title)

Journal of the Chemical Society, Chemical Communications

First Page

217

Last Page

218

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