Title

Protiodeacetylation of porphyrins and pyrroles: A new partial synthesis of dehydrocoproporphyrin (S411-porphyrin)

Document Type

Article

Publication Date

1-1-1981

Abstract

Treatment of copper(II) complexes of acetylporphyrins with ethanedithiol and boron trifluoride-ether in acetic acid efficiently accomplishes deacetylation of the porphyrin system, and this reaction is demonstrated in a new partial synthesis of dehydrocoproporphyrin (S411-porphyrin); acetylpyrroles are also quantitatively deacetylated under these conditions.

Publication Source (Journal or Book title)

Journal of the Chemical Society, Chemical Communications

First Page

283

Last Page

284

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