Title

Nickel(II)-promoted rearrangements of Some N-substituted porphyrins

Document Type

Article

Publication Date

1-1-1986

Abstract

Nickel(ll)-promoted rearrangement of an (N-methoxycarbonylmethy1)-substitutedp orphyrin (1) affords the nickel(ll) meso-methoxycarbonylmethylporphyrins, (3) and (4), produced by intramolecular migration of the N-substituent to carbon; when the pyrrole subunit containing the N-substituent also possesses a fi-methoxycarbonylmethyl group, 1e.g. compound (5)] a good yield of a nickel(rr) chlorin (7) is obtained. © Royal Society of Chemistry.

Publication Source (Journal or Book title)

Journal of the Chemical Society - Series Chemical Communications

First Page

1498

Last Page

1499

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