Title

Generation of a Stable σ-Bonded Iron(IV) Porphyrin. Formation and Reactivity of [(OETPP)FeIV(C6H5)]n+ (n = 1−3; OETPP = Dianion of 2,3,7,8,12,13,17,18-Octaethyl-5,10,15,20-Tetraphenylporphyrin)

Document Type

Article

Publication Date

1-1-1993

Abstract

This work reports the first generation and spectral characterization of a σ-bonded iron(IV) porphyrin which is stable in nonaqueous media at room temperature, as well as the first monomeric iron(III) porphyrin to undergo three reversible one-electron oxidations. It also gives the first example where the migration of a σ-bonded axial ligand occurs from a doubly and not singly oxidized iron porphyrin. © 1993, American Chemical Society. All rights reserved.

Publication Source (Journal or Book title)

Organometallics

First Page

2411

Last Page

2413

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