Title

5,10,15,20‐Tetra‐tert‐butylporphyrin and Its Remarkable Reactivity in the 5‐ and 15‐Positions

Document Type

Article

Publication Date

9-30-1994

Abstract

Owing to the steric bulk of the tert‐butyl groups, the reactivity of the novel porphyrin 1, which has a nonplanar macrocyclic framework, deviates distinctly from that of any other known porphyrin. For example, prolonged treatment of 1 in HClO4/MeOH leads to formation of 5,15‐dihydroporphyrin (“porphodi‐methene”) 2. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

Publication Source (Journal or Book title)

Angewandte Chemie International Edition in English

First Page

1879

Last Page

1881

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