Title

Axial coordination phenomena in highly substituted porphyrins. Crystal structure of the polymeric (2,3,7,8,12,13,17,18-octaethyl-5,10,15,20- tetranitroporphyrinato)zinc(II), [{Zn(oetnp)}n]

Document Type

Article

Publication Date

12-1-1994

Abstract

The polymeric structure of the sterically strained and non-planar porphyrin [{ZnIIoetnp}n] is determined by X-ray crystallography; polymerization is achieved by utilization of the nitro-groups for axial ligation to the zinc(II) centre.

Publication Source (Journal or Book title)

Journal of the Chemical Society, Chemical Communications

First Page

923

Last Page

924

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