Title
Structure and Conformation of Photosynthetic Pigments and Related Compounds 9 On the Structure and Macrocycle Conformation of Two Copper(II) Rhodochlorin Derivatives and Two Related Rhodoporphyrins
Document Type
Article
Publication Date
6-1-1995
Abstract
Crystal structure analyses of (rhodochlorinato-15-acetic trimethyl ester)copper(II) 3 and (31,32-didehydro-rhodochlorinato-15-formic acid trimethyl ester)copper(II) 4 reveal intriguing multiple macrocycle conformations of the metallochlorins in the crystal. The observed conformations range from almost planar macrocycles to distorted macrocycles with individual atoms being displaced up to 0.72 A from the mean plane. The nonplanar macrocycles show a S4-ruttled macrocycle distortion with significant distortions for the weso-carbons and tilting of the Cb–Cb axes. A comparison with the related free base porphyrins rhodoporphyrin-15-acetic acid trimethyl ester 5 and rhodoporphyrin dimethyl ester 6 shows that the conformational distortion is due to the mixing of metal and substituent effects, hydroporphyrin character, and packing forces. Crystal data: 3, monoclinic, P21, a = 12.096(4) A, b = 14.307(4) Å, c = 22.343(9) A, β = 104.94(4)°, Z = 4 (2 indep. mol.), R = 0,069 for 8141 reflections with I > 2.0a(I); 4, triclinic, P1, a = 10.528(3) A, b = 10.646(4) A, c = 34.026(13) A, a = 89.81(4)°, β = 88.72(3)°, y = 60.38(2)°, Z = 4 (4 indep. mol.), R = 0.073 for 9446 reflections with I > 2.5 σ(I); 5, triclinic, PĪ, a = 9.591(2) A, b = 12.959(4) A, c = 13.453(4) A, a = 105.86(2)°, β = 92.67(2)°, γ = 96.12(2)°, Z = 2. R = 0.060 for 4990 reflections with I > 2.5 σ(I); 6, triclinic, PĪ, a = 8.908(4) A, b = 12.895(5) A, c = 13.482(6) A, a = 102.74(3)°,β = 90.38(4)°, y = 91.84(3)°, Z = 2, R = 0.089 for 3369 reflections with I > 2.0σ(I). © 1995 Verlag der Zeitschrift für Naturforschung. All rights reserved.
Publication Source (Journal or Book title)
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
First Page
969
Last Page
981
Recommended Citation
Senge, M., Ruhlandt-Senge, K., Lee, S., & Smith, K. (1995). Structure and Conformation of Photosynthetic Pigments and Related Compounds 9 On the Structure and Macrocycle Conformation of Two Copper(II) Rhodochlorin Derivatives and Two Related Rhodoporphyrins. Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 50 (6), 969-981. https://doi.org/10.1515/znb-1995-0620