Nucleoside adducts of vinylporphyrins and vinylchlorins
Ethene-linked nucleoside derivatives of porphyrins and chlorins have been synthesized by palladium-catalysed coupling between acetylated 5-chloromercuriuridine and various vinylporphyrins and vinylchlorins. The formation of both the trans- (e.g. 22, 24, 29) and gem- (e.g. 23, 30) isomeric products was usually observed in these coupling reactions, and ratios of these isomers were dependent upon the particular substrate employed.
Publication Source (Journal or Book title)
Journal of the Chemical Society - Perkin Transactions 1
Jiang, X., Pandey, R., & Smith, K. (1996). Nucleoside adducts of vinylporphyrins and vinylchlorins. Journal of the Chemical Society - Perkin Transactions 1 (13), 1607-1615. https://doi.org/10.1039/p19960001607