"Rational approach to the synthesis of meso-meso (5,5′) linked bis-porp" by Richard G. Khoury, Laurent Jaquinod et al.

Faculty Publications

Title

Rational approach to the synthesis of meso-meso (5,5′) linked bis-porphyrins

Authors

Richard G. Khoury, University of California, Davis
Laurent Jaquinod, University of California, Davis
Kevin M. Smith, University of California, Davis

Document Type

Article

Publication Date

1-1-1997

Abstract

A novel approach for the synthesis of 5,5′-directly linked metal-free bis-porphyrins is reported; McMurry type coupling of dipyrroketones (e.g. 1) leads to 1,1,2,2-tetra(2-pyrrolyl)ethene 2, which after tetra-formylation (to give 3) and MacDonald macrocyclization with a 1,9-di-unsubstituted dihydrodipyrrin 4, affords the 5,5′-bis-porphyrin 5.

Publication Source (Journal or Book title)

Chemical Communications

First Page

1057

Last Page

1058

Recommended Citation

Khoury, R., Jaquinod, L., & Smith, K. (1997). Rational approach to the synthesis of meso-meso (5,5′) linked bis-porphyrins. Chemical Communications (11), 1057-1058. https://doi.org/10.1039/a701218g

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