Title

Vinyl group protection in porphyrins and chlorins: Organoselenium derivatives

Document Type

Article

Publication Date

2-10-1997

Abstract

The o-nitrophenylselenoethyl functionality is a useful protected vinyl group in porphyrins and chlorins, and its use is demonstrated in the Vilsmeier formylation reaction which has been shown to adversely affect unmodified vinyl groups in tetrapyrrole systems. The X-ray crystal structure for 3-(2-o-nitrophenylselenoethyl)-3-devinylchIorin-e6 trimethyl ester 14 is reported.

Publication Source (Journal or Book title)

Tetrahedron Letters

First Page

937

Last Page

940

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