Title
Facile synthesis of a bis-linked dioxocyclam porphyrin
Document Type
Article
Publication Date
1-1-1998
Abstract
Reaction of the 5,15-di-(2-alkylamidophenyl)-etioporphyrin 3 (α,α-atropisomer) with the 'self-trans-diprotected' dioxocyclam 4 leads easily, in only two steps, to a new symmetrical dioxocyclam porphyrin 5 in an overall 41% yield. This ligand is a precursor of models of cytochromes. All the compounds have been fully characterized by elemental analysis, mass spectrometry and UV-vis, 1H NMR, 13C NMR and 1H-13C heteronuclear correlation NMR spectroscopies. X-ray structural data are presented for the Zn(II) porphyrin 6 confirming that the porphyrin and the dioxocyclam adopt cofacial orientations. © 1998 John Wiley & Sons, Ltd.
Publication Source (Journal or Book title)
Journal of Porphyrins and Phthalocyanines
First Page
377
Last Page
382
Recommended Citation
Comte, C., Gros, C., Guilard, R., Khoury, R., & Smith, K. (1998). Facile synthesis of a bis-linked dioxocyclam porphyrin. Journal of Porphyrins and Phthalocyanines, 2 (4-5), 377-382. https://doi.org/10.1002/(sici)1099-1409(199807/10)2:4/5<377::aid-jpp93>3.0.co;2-#