Title

Effects of π-bonding on stability and reactivity in CpCr(NO)] complexes

Document Type

Article

Publication Date

5-2-2000

Abstract

Recent synthetic and theoretical investigations of organometallic compounds containing the CpCr(NO) fragment have shown an interdependence of the electronic nature of ancillary ligands and the stability of a given Cr oxidation state. Understanding the correlation between ligand π-bonding properties and the nature of the metal-based frontier orbitals permits the rationalization of observed reactivity patterns, and the identification and preparation of new classes of target molecules.

Publication Source (Journal or Book title)

Chemistry - A European Journal

First Page

1525

Last Page

1529

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