Title
Conformational landscape surfing induced by off-on φ-φ stacking in a porphyrin-quinone dyad
Document Type
Article
Publication Date
1-1-2002
Abstract
A covalently linked porphyrin-quinone dyad crystallizes with two orientations of the quinone, extended away from (off) and cofacial with the porphyrin macrocycle (on), which induce different conformations of the macrocycle and model the recently proposed structural effect of a nearby residue on the heme prosthetic group of a nitric oxide synthase.
Publication Source (Journal or Book title)
Chemical Communications
First Page
2982
Last Page
2983
Recommended Citation
Nurco, D., Smith, K., & Fajer, J. (2002). Conformational landscape surfing induced by off-on φ-φ stacking in a porphyrin-quinone dyad. Chemical Communications (24), 2982-2983. https://doi.org/10.1039/b209238g