Title

Conformational landscape surfing induced by off-on φ-φ stacking in a porphyrin-quinone dyad

Document Type

Article

Publication Date

1-1-2002

Abstract

A covalently linked porphyrin-quinone dyad crystallizes with two orientations of the quinone, extended away from (off) and cofacial with the porphyrin macrocycle (on), which induce different conformations of the macrocycle and model the recently proposed structural effect of a nearby residue on the heme prosthetic group of a nitric oxide synthase.

Publication Source (Journal or Book title)

Chemical Communications

First Page

2982

Last Page

2983

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