Title

A novel synthetic route to fused propenochlorin and benzochlorin photodynamic therapy probes

Document Type

Article

Publication Date

5-23-2002

Abstract

Reaction of meso-(2-formylvinyl)octaethylporphyrin with (CH3)3SiCN-Cu(OTf)2 produced unexpected 103-trimethylsiloxyl and 103-hydroxyl fused propenochlorins which, in H2SO4, underwent subsequent migration of the 8-ethyl group to the 103-position of the exocyclic benzene ring to form a novel benzochlorin.

Publication Source (Journal or Book title)

Chemical Communications

First Page

1172

Last Page

1173

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