Title

Synthesis and reactivity of chromium cyclopentadienyl β-diketiminato compounds

Document Type

Article

Publication Date

3-29-2004

Abstract

The activation of iodomethane by the Cr(II) complex 1 to form the Cr(III) iodide and Cr(III) methyl compounds 2 and 3 was monitored by UV-visible spectroscopy. The Cr(III) halide species were independently synthesized by oxidation of 1 with lead(II) halides, the Cr(III) methyl compound was prepared via salt metathesis of the Cr(III) triflate, and their structures were determined by single-crystal X-ray diffraction.

Publication Source (Journal or Book title)

Organometallics

First Page

1487

Last Page

1489

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