Title
Chromium(III) and chromium(IV) bis(trimethylsilyl)amido complexes as ethylene polymerisation catalysts
Document Type
Article
Publication Date
11-7-2004
Abstract
Oxidation of Cr[N(SiMe3)2]2(THF) 2 with iodine and dicumyl peroxide results in tetrahedral Cr(IV) Cr[N(SiMe3)2]2I2 and trigonal planar Cr(III) Cr[N(SiMe3)2](OCMe2Ph)2, respectively; both complexes have been characterised by single-crystal X-ray diffraction, and both are active for ethylene polymerisation with alkylaluminium co-catalysts.
Publication Source (Journal or Book title)
Dalton Transactions
First Page
3431
Last Page
3433
Recommended Citation
Ballern, K., Shetty, V., Etkin, N., Patrick, B., & Smith, K. (2004). Chromium(III) and chromium(IV) bis(trimethylsilyl)amido complexes as ethylene polymerisation catalysts. Dalton Transactions (21), 3431-3433. https://doi.org/10.1039/b412584c
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