Document Type
Article
Publication Date
7-28-2008
Abstract
(Chemical Equation Presented) Radicals in check: The steric properties of the aryl substituents in chromium β-ketiminato complexes can be tuned to achieve reversible radical trapping of a growing poly(vinyl acetate) radical chain (see scheme; V-70 = radical initiator, VOAc = vinyl acetate). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
Publication Source (Journal or Book title)
Angewandte Chemie - International Edition
First Page
6069
Last Page
6072
Recommended Citation
Champouret, Y., Baisch, U., Poli, R., Tang, L., Conway, J., & Smith, K. (2008). Homolytic bond strengths and formation rates in half-sandwich chromium alkyl complexes: Relevance for controlled radical polymerization. Angewandte Chemie - International Edition, 47 (32), 6069-6072. https://doi.org/10.1002/anie.200801498
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