Title

Homolytic bond strengths and formation rates in half-sandwich chromium alkyl complexes: Relevance for controlled radical polymerization

Document Type

Article

Publication Date

7-28-2008

Abstract

(Chemical Equation Presented) Radicals in check: The steric properties of the aryl substituents in chromium β-ketiminato complexes can be tuned to achieve reversible radical trapping of a growing poly(vinyl acetate) radical chain (see scheme; V-70 = radical initiator, VOAc = vinyl acetate). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

Publication Source (Journal or Book title)

Angewandte Chemie - International Edition

First Page

6069

Last Page

6072

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