Title

Generation of Binuclear (d8·d8)pσ Platinum and Rhodium Complexes by Pulse Radiolysis

Document Type

Article

Publication Date

9-1-1984

Abstract

Two (d8·d8)pσ binuclear complexes, Pt2(pop)45−(pop = P2O5H22−) and Rh2(TMB)4+(TMB = 2,5-dimethyl-2,5-diisocyanohexane), have been generated by pulse radiolysis of aqueous and acetonitrile solutions, respectively, of the corresponding d8·d8species. An intense absorption system attributable to the allowed dσ* → pσ transition is observed in the spectrum of each of the transients (420 nm, Pt2(pop)45−; 570 nm, Rh2(TMB)4+). © 1984, American Chemical Society. All rights reserved.

Publication Source (Journal or Book title)

Journal of the American Chemical Society

First Page

5143

Last Page

5145

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