Title

β-Pyrrolopyrazino Annulated Corroles via a Pictet-Spengler Approach

Document Type

Article

Publication Date

7-15-2016

Abstract

© 2016 American Chemical Society. Reaction of 2-amino-3-(pyrrol-1-yl)-5,10,15-tris(4-tert-butylphenyl)corrolato copper(II) with arylaldehydes affords novel π-extended β,β′-pyrrolo(1,2-a)pyrazino-fused corroles via a Pictet-Spengler reaction. Corrole shows an unprecedented reaction pathway, leading to a mixture of phenyl-substituted and nonsubstituted pyrrolopyrazino annulated species as reaction products.

Publication Source (Journal or Book title)

Organic Letters

First Page

3318

Last Page

3321

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