Title
β-Pyrrolopyrazino Annulated Corroles via a Pictet-Spengler Approach
Document Type
Article
Publication Date
7-15-2016
Abstract
© 2016 American Chemical Society. Reaction of 2-amino-3-(pyrrol-1-yl)-5,10,15-tris(4-tert-butylphenyl)corrolato copper(II) with arylaldehydes affords novel π-extended β,β′-pyrrolo(1,2-a)pyrazino-fused corroles via a Pictet-Spengler reaction. Corrole shows an unprecedented reaction pathway, leading to a mixture of phenyl-substituted and nonsubstituted pyrrolopyrazino annulated species as reaction products.
Publication Source (Journal or Book title)
Organic Letters
First Page
3318
Last Page
3321
Recommended Citation
Berionni Berna, B., Nardis, S., Galloni, P., Savoldelli, A., Stefanelli, M., Fronczek, F., Smith, K., & Paolesse, R. (2016). β-Pyrrolopyrazino Annulated Corroles via a Pictet-Spengler Approach. Organic Letters, 18 (14), 3318-3321. https://doi.org/10.1021/acs.orglett.6b01314