Title

Observation of Bridging and Terminal Metal Hydrides by Solid-State Deuterium NMR Spectroscopy: Application to Bis(cyclopentadienyl)zirconium Dideuteride

Document Type

Article

Publication Date

5-1-1987

Abstract

The solid-state deuterium NMR spectrum of [(η5-C5H5)2Zr2H2x has been measured at 46 and 61 MHz. Two deuterium sites were detected: a Zr-2H terminal bond and a Zr-2H-Zr bridging bond. The values found for the deuterium quadrupole coupling constant for the terminal and bridging sites are 46.7 (5) and 32.7 (20) kHz, respectively. A discussion is presented regarding assignment of deuterium quadrupole coupling constants to terminal or bridging metal hydride sites. © 1987, American Chemical Society. All rights reserved.

Publication Source (Journal or Book title)

Inorganic Chemistry

First Page

1381

Last Page

1383

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