Title
Observation of Bridging and Terminal Metal Hydrides by Solid-State Deuterium NMR Spectroscopy: Application to Bis(cyclopentadienyl)zirconium Dideuteride
Document Type
Article
Publication Date
5-1-1987
Abstract
The solid-state deuterium NMR spectrum of [(η5-C5H5)2Zr2H2x has been measured at 46 and 61 MHz. Two deuterium sites were detected: a Zr-2H terminal bond and a Zr-2H-Zr bridging bond. The values found for the deuterium quadrupole coupling constant for the terminal and bridging sites are 46.7 (5) and 32.7 (20) kHz, respectively. A discussion is presented regarding assignment of deuterium quadrupole coupling constants to terminal or bridging metal hydride sites. © 1987, American Chemical Society. All rights reserved.
Publication Source (Journal or Book title)
Inorganic Chemistry
First Page
1381
Last Page
1383
Recommended Citation
Jarrett, W., Farlee, R., & Butler, L. (1987). Observation of Bridging and Terminal Metal Hydrides by Solid-State Deuterium NMR Spectroscopy: Application to Bis(cyclopentadienyl)zirconium Dideuteride. Inorganic Chemistry, 26 (9), 1381-1383. https://doi.org/10.1021/ic00256a009