Yb3+ and Yb3+/Er3+ doping for near-infrared emission and improved stability of CsPbCl3 nanocrystals
© 2018 The Royal Society of Chemistry. Lead halide perovskite nanocrystals (NCs) exhibit excellent tunable emissions covering the entire visible spectral region, but they do not emit near-infrared (NIR) light. We synthesized rare earth element doped CsPbCl3 NCs for NIR emission. The Yb3+ doped CsPbCl3 NCs emitted strong 986 nm NIR light; the Yb3+/Er3+ co-doped CsPbCl3 NCs emitted at 1533 nm. The total photoluminescence quantum yield (PL QY) of the CsPbCl3 NCs changed from 5.0% to 127.8% upon incorporating 2.0% Yb3+, a factor of 25.6 times enhancement. The material's stability was tested under continuous ultraviolet (365 nm) irradiation. The doped CsPbCl3 NCs exhibited a better stability than the undoped one. The PL intensity of the undoped CsPbCl3 NCs dropped to 20% of the initial value in 27 h, while the doped one took 85 h.
Publication Source (Journal or Book title)
Journal of Materials Chemistry C
Zhang, X., Zhang, Y., Zhang, X., Yin, W., Wang, Y., Wang, H., Lu, M., Li, Z., Gu, Z., & Yu, W. (2018). Yb3+ and Yb3+/Er3+ doping for near-infrared emission and improved stability of CsPbCl3 nanocrystals. Journal of Materials Chemistry C, 10101-10105. https://doi.org/10.1039/c8tc03957g